Literature DB >> 14986955

Paradigm confirmed: the first use of ionic liquids to dramatically influence the outcome of chemical reactions.

Martyn J Earle1, Suhas P Katdare, Kenneth R Seddon.   

Abstract

It has been an unproven paradigm that the choice of which ionic liquid to use in a chemical reaction can have a dramatic effect on the outcome of that chemical reaction. We demonstrate, for the first time, that the reaction of toluene and nitric acid in three different ionic liquids gives rise to three completely different products in high yield. Furthermore, ionic liquids can catalyze these reactions with the only byproduct being water. [reaction: see text]

Entities:  

Year:  2004        PMID： 14986955     DOI： 10.1021/ol036310e

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  11 in total

1.  Small volume laboratory on a chip measurements incorporating the quartz crystal microbalance to measure the viscosity-density product of room temperature ionic liquids.

Authors:  N Doy; G McHale; M I Newton; C Hardacre; R Ge; J M Macinnes; D Kuvshinov; R W Allen
Journal:  Biomicrofluidics       Date:  2010-03-08       Impact factor: 2.800

Review 2.  Structural modifications of nucleosides in ionic liquids.

Authors:  Vineet Kumar; Virinder S Parmar; Sanjay V Malhotra
Journal:  Biochimie       Date:  2010-02-21       Impact factor: 4.079

3.  Green chemistry for chemical synthesis.

Authors:  Chao-Jun Li; Barry M Trost
Journal:  Proc Natl Acad Sci U S A       Date:  2008-09-03       Impact factor: 11.205

4.  The base-free chemoselective ring opening of epoxides with carboxylic acids using [bmim]Br: a rapid entry into 1,2-diol mono-esters synthesis.

Authors:  Mohammad Navid Soltani Rad; Somayeh Behrouz
Journal:  Mol Divers       Date:  2012-11-07       Impact factor: 2.943

Review 5.  Advances in QSPR/QSTR models of ionic liquids for the design of greener solvents of the future.

Authors:  Rudra Narayan Das; Kunal Roy
Journal:  Mol Divers       Date:  2013-01-17       Impact factor: 2.943

6.  Facile, efficient and one-pot access to diverse new functionalized aminoalkyl and amidoalkyl naphthol scaffolds via green multicomponent reaction using triethylammonium hydrogen sulfate ([Et3NH][HSO4]) as an acidic ionic liquid under solvent-free conditions.

Authors:  Elahe Hadadianpour; Behjat Pouramiri
Journal:  Mol Divers       Date:  2019-04-05       Impact factor: 2.943

7.  Green and four-component cyclocondensation synthesis and in silico docking of new polyfunctionalized pyrrole derivatives as the potential anticholinesterase agents.

Authors:  Mohammad Hadi Meshkatalsadat; Ahmad Mahmoudi; Safa Lotfi; Behjat Pouramiri; Alireza Foroumadi
Journal:  Mol Divers       Date:  2022-01-16       Impact factor: 2.943

8.  Ionic liquid promoted preparation of 4H-thiopyran and pyrimidine nucleoside-thiopyran hybrids through one-pot multi-component reaction of thioamide.

Authors:  Xinying Zhang; Xiaoyan Li; Xuesen Fan; Xia Wang; Dongfang Li; Guirong Qu; Jianji Wang
Journal:  Mol Divers       Date:  2008-12-09       Impact factor: 2.943

9.  Ionic liquids: just Molten salts after all?

Authors:  Hon Man Yau; Si Jia Chan; Stephen R D George; James M Hook; Anna K Croft; Jason B Harper
Journal:  Molecules       Date:  2009-07-13       Impact factor: 4.411

Review 10.  On the chemical stabilities of ionic liquids.

Authors:  Subbiah Sowmiah; Venkatesan Srinivasadesikan; Ming-Chung Tseng; Yen-Ho Chu
Journal:  Molecules       Date:  2009-09-25       Impact factor: 4.411
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