Literature DB >> 14765245

Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.

Nico Adams1, Henricus J Arts, Paul D Bolton, Dan Cowell, Stuart R Dubberley, Nic Friederichs, Craig M Grant, Mirko Kranenburg, Andrew J Sealey, Bing Wang, Paul J Wilson, Andrew R Cowley, Philip Mountford, Martin Schröder.   

Abstract

A family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me(3)[9]aneN(3))Cl(2)](R = alkyl or aryl; Me(3)[9]aneN(3)= 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation precatalysts with activities in the range ca. 3 400 to 10 000 kg(PE) mol(-1) h(-1) bar(-1).

Entities:  

Year:  2004        PMID: 14765245     DOI: 10.1039/b313921b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Titanium Imido Complexes via Displacement of -SiMe3 and C-H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC).

Authors:  Qing Ye; Micah S Ziegler; K V Lakshmi; T Don Tilley
Journal:  Eur J Inorg Chem       Date:  2017-05-11       Impact factor: 2.524

2.  Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes.

Authors:  Neil C Tomson; John Arnold; Robert G Bergman
Journal:  Organometallics       Date:  2010-11-08       Impact factor: 3.876

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.