Literature DB >> 14759184

Radical-type reactivity of the 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyl.

Hideki Amii1, Lidija Vranicar, Heinz Gornitzka, Didier Bourissou, Guy Bertrand.   

Abstract

Despite through-space and through-bond B-B interactions, the stable 1,3-bora-2,4-diphosphoniocyclobutane-1,3-diyl displays some radical-type behavior, as illustrated by the spontaneous formation of the trans 1,3-adduct with trimethyltin hydride and a B-spiro derivative with bromotrichloromethane.

Entities:  

Year:  2004        PMID： 14759184     DOI： 10.1021/ja039920i

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Main-group elements as transition metals.

Authors:  Philip P Power
Journal:  Nature       Date:  2010-01-14       Impact factor: 49.962

2.  An NHC-Stabilized H2 GeBH2 Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains.

Authors:  Matthias T Ackermann; Michael Seidl; Fuwei Wen; Michael J Ferguson; Alexey Y Timoshkin; Eric Rivard; Manfred Scheer
Journal:  Chemistry       Date:  2021-11-24       Impact factor: 5.020

3.  Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P-B-P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate.

Authors:  Natalia Szynkiewicz; Anna Ordyszewska; Jarosław Chojnacki; Rafał Grubba
Journal:  Inorg Chem       Date:  2021-03-03       Impact factor: 5.165

4.  Radical Reactivity of the Biradical [⋅P(μ-NTer)2 P⋅] and Isolation of a Persistent Phosphorus-Cantered Monoradical [⋅P(μ-NTer)2 P-Et].

Authors:  Jan Rosenboom; Lukas Chojetzki; Tim Suhrbier; Jabor Rabeah; Alexander Villinger; Ronald Wustrack; Jonas Bresien; Axel Schulz
Journal:  Chemistry       Date:  2022-05-19       Impact factor: 5.020

5.  Zwitterionic and biradicaloid heteroatomic cyclopentane derivatives containing different group 15 elements.

Authors:  Alexander Hinz; Axel Schulz; Alexander Villinger
Journal:  Chem Sci       Date:  2015-10-27       Impact factor: 9.825
  5 in total

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