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Literature DB >> 14754072

Enhanced ionic conductivity of polymer electrolytes containing nanocomposite SiO2 particles.

Ce-Wen Nan¹, Lizhen Fan, Yuanhua Lin, Qiang Cai.

Abstract

We report a new kind of polyethlene oxide (PEO)-Li based composite polymer electrolyte containing active nanocomposite particles with ethylene carbonate (EC)/propylene carbonate (PC) plasticizers embedded in mesoporous SiO2 (EC/PC-SiO2). A very large enhancement of the ionic conductivity was observed for the PEO-Li/(EC/PC-SiO2) electrolytes. This could be attributed mainly to conducting EC/PC nanochannels in the active nanocomposite particles. This unique mechanism is absent in currently known nanocomposite polymer electrolytes with inert oxide nanoparticles. Both high ionic conductivity and excellent stability of such new nanocomposite polymer electrolytes potentially makes it one of the most promising electrolyte materials.

Entities: Chemical

Year: 2003 PMID： 14754072 DOI： 10.1103/PhysRevLett.91.266104

Source DB: PubMed Journal: Phys Rev Lett ISSN： 0031-9007 Impact factor: 9.161

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Cited

9 in total

Enhanced ionic conductivity of polymer electrolytes containing nanocomposite SiO2 particles.

Review 1. Review on Polymer-Based Composite Electrolytes for Lithium Batteries.

2. Probing the Dynamics of Li⁺ Ions on the Crystal Surface: A Solid-State NMR Study.

3. Strong and Flexible Composite Solid Polymer Electrolyte Membranes for Li-Ion Batteries.

Review 4. Development and Progression of Polymer Electrolytes for Batteries: Influence of Structure and Chemistry.

5. Improved Performance of All-Solid-State Lithium Metal Batteries via Physical and Chemical Interfacial Control.

6. Lithium-ion transport in inorganic active fillers used in PEO-based composite solid electrolyte sheets.

Review 7. The Impact of Polymer Electrolyte Properties on Lithium-Ion Batteries.

8. Cold Sintering of Li_6.4La₃Zr_1.4Ta_0.6O₁₂/PEO Composite Solid Electrolytes.

9. Solid Polymer Electrolytes with Flexible Framework of SiO₂ Nanofibers for Highly Safe Solid Lithium Batteries.

Enhanced ionic conductivity of polymer electrolytes containing nanocomposite SiO2 particles.

Review 1. Review on Polymer-Based Composite Electrolytes for Lithium Batteries.

2. Probing the Dynamics of Li+ Ions on the Crystal Surface: A Solid-State NMR Study.

3. Strong and Flexible Composite Solid Polymer Electrolyte Membranes for Li-Ion Batteries.

Review 4. Development and Progression of Polymer Electrolytes for Batteries: Influence of Structure and Chemistry.

5. Improved Performance of All-Solid-State Lithium Metal Batteries via Physical and Chemical Interfacial Control.

6. Lithium-ion transport in inorganic active fillers used in PEO-based composite solid electrolyte sheets.

Review 7. The Impact of Polymer Electrolyte Properties on Lithium-Ion Batteries.

8. Cold Sintering of Li6.4La3Zr1.4Ta0.6O12/PEO Composite Solid Electrolytes.

9. Solid Polymer Electrolytes with Flexible Framework of SiO2 Nanofibers for Highly Safe Solid Lithium Batteries.

2. Probing the Dynamics of Li⁺ Ions on the Crystal Surface: A Solid-State NMR Study.

8. Cold Sintering of Li_6.4La₃Zr_1.4Ta_0.6O₁₂/PEO Composite Solid Electrolytes.

9. Solid Polymer Electrolytes with Flexible Framework of SiO₂ Nanofibers for Highly Safe Solid Lithium Batteries.