| Literature DB >> 14753801 |
Dorothea Fiedler1, Daniela Pagliero, Julia L Brumaghim, Robert G Bergman, Kenneth N Raymond.
Abstract
A chiral supramolecular assembly encapsulates the two cationic ruthenium sandwich complexes [CpRu(eta(6)-C(6)H(6))](+) and [CpRu(p-cymene)](+). The host-guest complexes K(11)[CpRu(eta(6)-C(6)H(6)) subset Ga(4)L(6)] (2) and K(11)[CpRu(p-cymene) subset Ga(4)L(6)] (3) were characterized by one- and two-dimensional NMR techniques as well as by electrospray mass spectrometry. Encapsulation of the prochiral complex [CpRu(p-cymene)](+) by the chiral host renders enantiotopic protons diastereotopic as evidenced by (1)H NMR spectroscopy.Entities:
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Year: 2004 PMID： 14753801 DOI： 10.1021/ic035105s
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165