Literature DB >> 14750832

Reactions of a carbamoylstannane with acid chlorides: highly efficient synthesis of alpha-oxo amides.

Ruimao Hua1, Hide-aki Takeda, Yoshimoto Abe, Masato Tanaka.   

Abstract

Treatment of acid chlorides with a carbamoylstannane under mild conditions (mostly rt for a few hours) affords alpha-oxo amides in high yields. Vicinal polycarbonyl compounds are also obtained, although spontaneous decarbonylation occasionally occurs.

Entities:  

Year:  2004        PMID： 14750832     DOI： 10.1021/jo035572r

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Synthesis of alpha-keto-imides via oxidation of ynamides.

Authors:  Ziyad F Al-Rashid; Whitney L Johnson; Richard P Hsung; Yonggang Wei; Pei-Yuan Yao; Renhei Liu; Kang Zhao
Journal:  J Org Chem       Date:  2008-10-21       Impact factor: 4.354

2.  Selenium dioxide-mediated synthesis of α-ketoamides from arylglyoxals and secondary amines.

Authors:  Arthur Y Shaw; Christine R Denning; Christopher Hulme
Journal:  Tetrahedron Lett       Date:  2012-06-06       Impact factor: 2.415
  2 in total

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