Literature DB >> 14748607

Cyclizations of N-stannylaminyl radicals onto nitriles.

Luisa Benati1, Giorgio Bencivenni, Rino Leardini, Matteo Minozzi, Daniele Nanni, Rosanna Scialpi, Piero Spagnolo, Giuseppe Zanardi, Corrado Rizzoli.   

Abstract

[reaction: see text] Stannylaminyl radicals derived from radical reactions of Bu(3)SnH with azidoalkylmalononitriles exhibit highly efficient 5- and 6-exo cyclization onto either nitrile group to give aminoiminyl radicals that in turn are reduced to amidines or undergo successive 5-exo cyclization onto an internal alkene.

Entities:  

Year:  2004        PMID: 14748607     DOI: 10.1021/ol036268n

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  EPR and pulsed ENDOR study of intermediates from reactions of aromatic azides with group 13 metal trichlorides.

Authors:  Giorgio Bencivenni; Riccardo Cesari; Daniele Nanni; Hassane El Mkami; John C Walton
Journal:  Beilstein J Org Chem       Date:  2010-08-09       Impact factor: 2.883

  1 in total

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