| Literature DB >> 14748605 |
Katsufumi Suzuki1, Kohei Inomata, Yasuyuki Endo.
Abstract
[reaction: see text] An enantiocontrolled synthesis of (-)-methyl 6-epi-cucurbate and (+)-methyl jasmonate was established from a chiral tricyclic lactone via a new type of tandem retro-Diels-Alder-ene reaction activated by a trimethysilyl substituent as the key step.Entities:
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Year: 2004 PMID： 14748605 DOI： 10.1021/ol036253p
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005