Literature DB >> 14747853

Palladium-catalyzed addition of disulfides and diselenides to alkynes under solvent free conditions.

Valentine P Ananikov1, Irina P Beletskaya.   

Abstract

An efficient methodology was developed for performing palladium-catalyzed E-E (E = S, Se) bond addition to alkynes under solvent free conditions. Compared to reaction in solvent significant enhancement of reaction rate, improved efficiency and remarkable catalyst stability were observed under solvent free conditions. The addition reactions were carried out with high stereoselectivity and yields in a short reaction time.

Entities:  

Year:  2003        PMID: 14747853     DOI: 10.1039/b312471a

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  2 in total

1.  Unconventional Reactivity of Ethynylbenziodoxolone Reagents and Thiols: Scope and Mechanism.

Authors:  Bin Liu; Juan V Alegre-Requena; Robert S Paton; Garret M Miyake
Journal:  Chemistry       Date:  2020-01-22       Impact factor: 5.236

Review 2.  Metal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and Dienes.

Authors:  Nikolai V Orlov
Journal:  ChemistryOpen       Date:  2015-09-09       Impact factor: 2.911

  2 in total

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