| Literature DB >> 14737569 |
Philip L Callaghan1, Rodrigo Fernández-Pacheco, Naser Jasim, Sébastien Lachaize, Todd B Marder, Robin N Perutz, Eleonora Rivalta, Sylviane Sabo-Etienne.
Abstract
Metal phosphine hydrides of type RuP(4)H(2) and RhP(3)H(3) react photochemically with HB(pin)(pin = pinacolate) to form metal boryl hydride complexes via 16-electron intermediates generated by H(2) loss; the second order rate constants for reaction of the intermediates with HB(pin) are even larger than those for reaction with Et(3)SiH.Entities:
Year: 2003 PMID： 14737569 DOI： 10.1039/b312246h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222