Literature DB >> 14737529

Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems.

Andrei N Vedernikov1, Kenneth G Caulton.   

Abstract

Mild catalytic dehydrogenation of cycloalkanes (cyclo-C(5)H(10), cyclo-C(6)H(12), cyclo-C(8)H(16)) and aziridination of resulting olefins is reported with PhINTs and copper-[2.1.1]-(2,6)-pyridinophane (L) complexes LCuX(n)(n= 1, 2; X = Cl, OTf)"activated" with NaBAr(F)(4) in dichloromethane solution.

Entities:  

Year:  2003        PMID： 14737529     DOI： 10.1039/b309519c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Regioselective C-H bond amination by aminoiodanes.

Authors:  Abhishek A Kantak; Louis Marchetti; Brenton DeBoef
Journal:  Chem Commun (Camb)       Date:  2015-02-28       Impact factor: 6.222

2.  Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.

Authors:  Ly Dieu Tran; James Roane; Olafs Daugulis
Journal:  Angew Chem Int Ed Engl       Date:  2013-04-24       Impact factor: 15.336

3.  Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes.

Authors:  Pericles Stavropoulos
Journal:  Comments Mod Chem A Comments Inorg Chem       Date:  2016-04-29       Impact factor: 4.533

4.  Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes.

Authors:  Ba L Tran; Matthias Driess; John F Hartwig
Journal:  J Am Chem Soc       Date:  2014-11-24       Impact factor: 15.419
  4 in total

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