Literature DB >> 14737362

A new synthesis of 1,3-dihydrobenzo[1,2]oxasiloles by a novel rearrangement of a pentavalent silicon intermediate.

George Bashiardes1, Vanessa Chaussebourg, Géraldine Laverdan, Jacques Pornet.   

Abstract

A new synthesis of benzo[1,2]oxasiloles is described, wherein an unprecedented intramolecular allylic transposition takes place probably involving a pentavalent silicon intermediate.

Entities:  

Year:  2003        PMID: 14737362     DOI: 10.1039/b311804e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation.

Authors:  Eric M Simmons; John F Hartwig
Journal:  J Am Chem Soc       Date:  2010-11-15       Impact factor: 15.419

2.  Si-based benzylic 1,4-rearrangement/cyclization reaction.

Authors:  Barry M Trost; Andreas Bertogg
Journal:  Org Lett       Date:  2009-02-05       Impact factor: 6.005

  2 in total

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