Literature DB >> 14733533

Isolation of a stable covalent selenium azide RSeN3.

Thomas M Klapötke1, Burkhard Krumm, Kurt Polborn.   

Abstract

The first covalent selenium azide 2-Me2NCH2C6H4SeN3 has been synthesized and fully characterized including crystal structure determination. As shown by the experimental results, the relative stability of RSeN3 highly depends on the nature of the coordinating ability of the substituent R, resulting in a heterocyclic zwitterionic structure.

Entities:  

Year:  2004        PMID: 14733533     DOI: 10.1021/ja038975h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

1.  The synthesis and crystal structure of 2-(chloro-selan-yl)pyridine 1-oxide: the first monomeric organoselenenyl chloride stabilized by an intra-molecular secondary Se⋯O inter-action.

Authors:  Rizvan K Askerov; Zhanna V Matsulevich; Galina N Borisova; Svetlana A Zalepkina; Vasiliy F Smirnov; Maria M Grishina; Pavel V Dorovatovskii; Alexander V Borisov; Victor N Khrustalev
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-11-30
  1 in total

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