Literature DB >> 14730996

Pushing the frontiers of hard and soft scorpionate chemistry.

Christopher A Dodds1, Alan R Kennedy, John Reglinski, Mark D Spicer.   

Abstract

The preparation and structure of the first scorpionate complex of a group 16 element, [Te(kappa(2)-Tm(Me))(2)], is reported. It displays square planar geometry at the Te atom and two distinct ligand conformations. In addition, the first pyrazolylborate complex of a group 15 element, [Bi(Tp)(2)(pzH)Cl], has been synthesized and characterized.

Entities:  

Year:  2004        PMID： 14730996     DOI： 10.1021/ic035167i

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Mono- and binuclear tris(3-tert-butyl-2-sulfanylidene-1H-imidazol-1-yl)hydroborate bismuth(III) dichloride complexes: a soft scorpionate ligand can coordinate to p-block elements.

Authors:  Kiyoshi Fujisawa; Ayaka Kuboniwa; Mercedesz Kiss; Robert K Szilagyi
Journal:  Acta Crystallogr C Struct Chem       Date:  2016-10-05       Impact factor: 1.172

2.  The nature of the chemical bond in linear three-body systems: from i3- to mixed chalcogen/halogen and trichalcogen moieties.

Authors:  M Carla Aragoni; Massimiliano Arca; Francesco A Devillanova; Alessandra Garau; Francesco Isaia; Vito Lippolis; Annalisa Mancini
Journal:  Bioinorg Chem Appl       Date:  2007       Impact factor: 7.778
  2 in total

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