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Literature DB >> 14723553

A new and efficient method for the synthesis of trifluoromethylthio- and selenoethers.

Chaya Pooput¹, Maurice Medebielle, William R Dolbier.

Abstract

[reaction: see text] A new atom-economic procedure for preparation of trifluoromethyl thio- and selenoethers is reported, wherein both halves of aryl and alkyl disulfides and diselenides are able to be utilized with high efficiency.

Entities: Chemical

Year: 2004 PMID： 14723553 DOI： 10.1021/ol036303q

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

11 in total

1. Pd-catalyzed synthesis of Ar-SCF3 compounds under mild conditions.

Authors: Georgiy Teverovskiy; David S Surry; Stephen L Buchwald
Journal: Angew Chem Int Ed Engl Date: 2011-06-20 Impact factor: 15.336

2. Difluorocarbene-Derived Trifluoromethylthiolation and [(18)F]Trifluoromethylthiolation of Aliphatic Electrophiles.

Authors: Jian Zheng; Lu Wang; Jin-Hong Lin; Ji-Chang Xiao; Steven H Liang
Journal: Angew Chem Int Ed Engl Date: 2015-09-21 Impact factor: 15.336

3. Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation.

Authors: Vladimir N Boiko
Journal: Beilstein J Org Chem Date: 2010-08-18 Impact factor: 2.883

4. Discovery and development of organic super-electron-donors.

Authors: John A Murphy
Journal: J Org Chem Date: 2014-03-25 Impact factor: 4.354

5. Nickel-catalyzed trifluoromethylthiolation of Csp²-O bonds.

Authors: Alexander B Dürr; Guoyin Yin; Indrek Kalvet; François Napoly; Franziska Schoenebeck
Journal: Chem Sci Date: 2015-10-30 Impact factor: 9.825

6. When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides.

Authors: Indrek Kalvet; Qianqian Guo; Graham J Tizzard; Franziska Schoenebeck
Journal: ACS Catal Date: 2017-01-31 Impact factor: 13.084

A new and efficient method for the synthesis of trifluoromethylthio- and selenoethers.

1. Pd-catalyzed synthesis of Ar-SCF3 compounds under mild conditions.

2. Difluorocarbene-Derived Trifluoromethylthiolation and [(18)F]Trifluoromethylthiolation of Aliphatic Electrophiles.

3. Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation.

4. Discovery and development of organic super-electron-donors.

5. Nickel-catalyzed trifluoromethylthiolation of Csp²-O bonds.

6. When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides.

7. Trifluoromethyl Vinyl Sulfide: A Building Block for the Synthesis of CF₃S-Containing Isoxazolidines.

8. Original Synthesis of Fluorenyl Alcohol Derivatives by Reductive Dehalogenation Initiated by TDAE.

9. Metal-Free Regiodivergent Addition of Carbon Nucleophiles to α,β-Unsaturated Electrophiles.

10. Electrophilic Trifluoromethylselenolation of Boronic Acids.