Literature DB >> 14723516

Asymmetric hydrocyanation of hydrazones catalyzed by lanthanide--PYBOX complexes.

John M Keith1, Eric N Jacobsen.   

Abstract

[reaction: see text] The asymmetric addition of HCN to hydrazones is catalyzed in high yield and good-to-excellent enantioselectivity by the easily prepared (PhPYBOX)ErCl3 complex. This constitutes the first example of asymmetric catalytic hydrocyanation of hydrazones.

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Year:  2004        PMID: 14723516     DOI: 10.1021/ol035844c

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Chiral poly-rare earth metal complexes in asymmetric catalysis.

Authors:  Masakatsu Shibasaki
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2006-04       Impact factor: 3.493

2.  Synthesis and spectroscopic properties of new azo dyes derived from 3-ethylthio-5-cyanomethyl-4-phenyl-1,2,4-triazole.

Authors:  Mariam Al-Sheikh; Hanadi Y Medrasi; Kamal Usef Sadek; Ramadan Ahmed Mekheimer
Journal:  Molecules       Date:  2014-03-07       Impact factor: 4.411

  2 in total

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