| Literature DB >> 14719911 |
Shutaro Osa1, Takafumi Kido, Naohide Matsumoto, Nazzareno Re, Andrzej Pochaba, Jerzy Mrozinski.
Abstract
We report now the first single molecule magnet (SMM) consisting of d-f elements. The present study demonstrates that the synthesis of the d-f polynuclear molecule is a very promising approach to SMMs. (1) The d-f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component.Entities:
Year: 2004 PMID: 14719911 DOI: 10.1021/ja037365e
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419