| Literature DB >> 14709070 |
Sheryl L Wiskur1, Alexander Korte, Gregory C Fu.
Abstract
This report establishes that simple, "ligandless" palladium complexes can catalyze the first zirconium-Negishi reactions of alkyl electrophiles. In view of the attractiveness of ligandless catalysts (cost, simplicity, and ease of purification), these observations add a significant and intriguing new dimension to the development of effective palladium-based processes for coupling alkyl electrophiles.Entities:
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Year: 2004 PMID： 14709070 DOI： 10.1021/ja0393729
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419