Literature DB >> 14706740

Thermotropic and lyotropic properties of long chain alkyl glycopyranosides: part III: pH-sensitive headgroups.

G Milkereit1, M Morr, J Thiem, V Vill.   

Abstract

As part of a series of papers, the influence of carbohydrate headgroups and aliphatic chains on the mesogenic properties of glycolipids was investigated. Alkyl glycosides with different types of aliphatic chains were synthesised. Neutral glycolipids were oxidized to their uronic acid derivatives, using the well established TEMPO-oxidation. For comparison a 6-deoxy-6-amino alkylglucopyranoside was synthesised. In addition, the thermotropic and lyotropic phase behaviour of the synthesised compounds were investigated. The thermotropism was characterised by polarising microscopy, the lyotropism by the contact preparation method.

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Year:  2004        PMID: 14706740     DOI: 10.1016/j.chemphyslip.2003.09.007

Source DB:  PubMed          Journal:  Chem Phys Lipids        ISSN: 0009-3084            Impact factor:   3.329


  5 in total

1.  Dodecyl Amino Glucoside Enhances Transdermal and Topical Drug Delivery via Reversible Interaction with Skin Barrier Lipids.

Authors:  Monika Kopečná; Miloslav Macháček; Eva Prchalová; Petr Štěpánek; Pavel Drašar; Martin Kotora; Kateřina Vávrová
Journal:  Pharm Res       Date:  2017-01-09       Impact factor: 4.200

Review 2.  Astonishing diversity of natural surfactants: 1. Glycosides of fatty acids and alcohols.

Authors:  Valery M Dembitsky
Journal:  Lipids       Date:  2004-10       Impact factor: 1.880

3.  Hydrophobic tail length, degree of fluorination and headgroup stereochemistry are determinants of the biocompatibility of (fluorinated) carbohydrate surfactants.

Authors:  Xueshu Li; Jaroslav Turánek; Pavlína Knötigová; Hana Kudlácková; Josef Masek; Sean Parkin; Stephen E Rankin; Barbara L Knutson; Hans-Joachim Lehmler
Journal:  Colloids Surf B Biointerfaces       Date:  2009-05-05       Impact factor: 5.268

4.  Self-Organisation, Thermotropic and Lyotropic Properties of Glycolipids Related to their Biological Implications.

Authors:  Patrick Garidel; Yani Kaconis; Lena Heinbockel; Matthias Wulf; Sven Gerber; Ariane Munk; Volkmar Vill; Klaus Brandenburg
Journal:  Open Biochem J       Date:  2015-08-31

5.  Thermotropic and lyotropic behaviour of new liquid-crystalline materials with different hydrophilic groups: synthesis and mesomorphic properties.

Authors:  Alexej Bubnov; Miroslav Kašpar; Věra Hamplová; Ute Dawin; Frank Giesselmann
Journal:  Beilstein J Org Chem       Date:  2013-02-25       Impact factor: 2.883

  5 in total

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