Literature DB >> 14703848

A diatropic ring current in a fluorofullerene trannulene.

Glenn A Burley1, Patrick W Fowler, Alessandro Soncini, John P B Sandall, Roger Taylor.   

Abstract

Ipsocentric current-density maps for a fluorofullerene derivative, C60F15H3, modelling the addition pattern of the experimentally characterised C60F15[CBr(CO2Et)2]3 which contains an [18]trans-annulene system, reveal a diamagnetic ring current dominated by the contribution of the four HOMO electrons, as in a classical (4n + 2) aromatic annulene.

Entities:  

Year:  2003        PMID: 14703848     DOI: 10.1039/b307514c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Synthesis and regiochemistry of [60]fullerenyl 2-methylmalonate bisadducts and their facile electron-accepting properties.

Authors:  Ken Kokubo; Riyah S Arastoo; Takumi Oshima; Chun-Chih Wang; Yuan Gao; Hsing-Lin Wang; Hao Geng; Long Y Chiang
Journal:  J Org Chem       Date:  2010-07-02       Impact factor: 4.354

  1 in total

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