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Literature DB >> 14703813

Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch.

Christopher D Ablan¹, Jason P Hallett, Kevin N West, Rebecca S Jones, Charles A Eckert, Charles L Liotta, Philip G Jessop.

Abstract

A method for fluorous biphasic catalysis is described,in which the fluorous liquid is replaced by fluorinated silica, the fluorous catalyst is induced to dissolve in the organic solvent by the presence of CO2, and the recovery of the catalyst after the reaction is achieved by release of the CO2 pressure.

Entities: Chemical

Year: 2003 PMID： 14703813 DOI： 10.1039/b311146f

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

1 in total

1. Sustainable Synthesis of Dimethyl- and Diethyl Carbonate from CO₂ in Batch and Continuous Flow-Lessons from Thermodynamics and the Importance of Catalyst Stability.

Authors: Matthew F O'Neill; Meenakshisundaram Sankar; Ulrich Hintermair
Journal: ACS Sustain Chem Eng Date: 2022-04-12 Impact factor: 9.224

1 in total

Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch.

1. Sustainable Synthesis of Dimethyl- and Diethyl Carbonate from CO2 in Batch and Continuous Flow-Lessons from Thermodynamics and the Importance of Catalyst Stability.

1. Sustainable Synthesis of Dimethyl- and Diethyl Carbonate from CO₂ in Batch and Continuous Flow-Lessons from Thermodynamics and the Importance of Catalyst Stability.