Literature DB >> 14703341

Highly selective asymmetric acetate aldol reactions of an N-acetyl thiazolidinethione reagent.

Yingchao Zhang1, Andrew J Phillips, Tarek Sammakia.   

Abstract

[reaction: see text] A highly diastereoselective acetate aldol reaction that uses a tert-leucine-derived thiazolidinethione auxiliary and dichlorophenylborane has been developed. The reaction proceeds in excellent yields and with high diastereoselectivities (drs range from 9.5:1 to >100:1).

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Year:  2004        PMID： 14703341     DOI： 10.1021/ol036020y

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  8 in total

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