| Literature DB >> 14692750 |
Ermelinda M S Maçôas1, Leonid Khriachtchev, Mika Pettersson, Rui Fausto, Markku Räsänen.
Abstract
The high-energy conformer of acetic acid (cis-AA) is produced in an Ar matrix by vibrational excitation of the OH stretching overtone of the ground conformational state (trans-AA). IR-absorption spectroscopy provides a clear identification of the reaction product. cis-AA converts back to trans-AA in a time scale of minutes at 8 K by tunneling.Entities:
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Year: 2003 PMID： 14692750 DOI： 10.1021/ja038341a
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419