Literature DB >> 14683192

What does the potential energy landscape tell us about the dynamics of supercooled liquids and glasses?

B Doliwa1, A Heuer.   

Abstract

For a model glass former we demonstrate via computer simulations how macroscopic dynamic quantities can be inferred from a potential energy landscape (PEL) analysis. The essential step is to consider whole superstructures of many PEL minima, called metabasins, rather than single minima. We show that two types of metabasins exist: some allowing for quasifree motion on the PEL (liquidlike), and the others acting as traps (solidlike). The activated, multistep escapes from the latter metabasins are found to dictate the slowing down of dynamics upon cooling over a much broader temperature range than is currently assumed.

Year:  2003        PMID: 14683192     DOI: 10.1103/PhysRevLett.91.235501

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  6 in total

1.  On the potential energy landscape of supercooled liquids and glasses.

Authors:  D Rodney; T Schrøder
Journal:  Eur Phys J E Soft Matter       Date:  2011-09-26       Impact factor: 1.890

2.  Molecular dynamics studies of heterogeneous dynamics and dynamic crossover in supercooled atomic liquids.

Authors:  Hans C Andersen
Journal:  Proc Natl Acad Sci U S A       Date:  2005-05-03       Impact factor: 11.205

3.  Evidence of a two-state picture for supercooled water and its connections with glassy dynamics.

Authors:  G A Appignanesi; J A Rodriguez Fris; F Sciortino
Journal:  Eur Phys J E Soft Matter       Date:  2009-07-16       Impact factor: 1.890

4.  Structure and dynamics of high- and low-density water molecules in the liquid and supercooled regimes.

Authors:  Joan Manuel Montes de Oca; J Ariel Rodriguez Fris; Sebastián R Accordino; David C Malaspina; Gustavo A Appignanesi
Journal:  Eur Phys J E Soft Matter       Date:  2016-12-15       Impact factor: 1.890

Review 5.  Predictive landscapes hidden beneath biological cellular automata.

Authors:  Lars Koopmans; Hyun Youk
Journal:  J Biol Phys       Date:  2021-11-05       Impact factor: 1.365

6.  Revisiting the concept of activation in supercooled liquids.

Authors:  Marco Baity-Jesi; Giulio Biroli; David R Reichman
Journal:  Eur Phys J E Soft Matter       Date:  2021-06-14       Impact factor: 1.890

  6 in total

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