Literature DB >> 14680239

Synthesis of novel axially chiral Rh-NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones.

Wei-Liang Duan1, Min Shia, Guo-Bin Rong.   

Abstract

Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee.

Entities:  

Year:  2003        PMID： 14680239     DOI： 10.1039/b309185f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Application of a C2-symmetric copper carbenoid in the enantioselective hydrosilylation of dialkyl and aryl-alkyl ketones.

Authors:  Abigail Albright; Robert E Gawley
Journal:  J Am Chem Soc       Date:  2011-11-16       Impact factor: 15.419

2.  (R)-N,N'-Dimethyl-1,1'-binaphthyldiamine.

Authors:  Scott E Denmark; Pavel G Ryabchuk
Journal:  Organic Synth       Date:  2019-09-27

3.  Design and synthesis of C2-symmetric N-heterocyclic carbene precursors and metal carbenoids.

Authors:  Abigail Albright; Daniel Eddings; Regina Black; Christopher J Welch; Nikolay N Gerasimchuk; Robert E Gawley
Journal:  J Org Chem       Date:  2011-08-25       Impact factor: 4.354

4.  Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes.

Authors:  Joan Vignolle; Heinz Gornitzka; Bruno Donnadieu; Didier Bourissou; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

5.  Synthesis of chiral mono(N-heterocyclic carbene) palladium and gold complexes with a 1,1'-biphenyl scaffold and their applications in catalysis.

Authors:  Lian-Jun Liu; Feijun Wang; Wenfeng Wang; Mei-Xin Zhao; Min Shi
Journal:  Beilstein J Org Chem       Date:  2011-05-04       Impact factor: 2.883

6.  Application of Chan-Lam cross coupling for the synthesis of N-heterocyclic carbene precursors bearing strong electron donating or withdrawing groups.

Authors:  Liliang Huang; Chengxiang He; Zhihua Sun
Journal:  Sci Rep       Date:  2015-07-23       Impact factor: 4.379

7.  Enantioselective hydrosilylation of unsaturated carbon-heteroatom bonds (C[double bond, length as m-dash]N, C[double bond, length as m-dash]O) catalyzed by [Ru-S] complexes: a theoretical study.

Authors:  Miao-Miao Zhou; Guanghui Chen; Li Dang
Journal:  RSC Adv       Date:  2020-03-04       Impact factor: 4.036
  7 in total

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