| Literature DB >> 14677928 |
Hiromitsu Maeda1, Atsuhiro Osuka, Hiroyuki Furuta.
Abstract
A trans type of doubly N-confused isomer of NCP (trans-N2CP) was synthesized via N-confused fused porphyrin (NcFP). The aromatic feature of trans-N2CP due to 18pi electronic system is contrasted to the weak aromaticity of cis-derivative. The solid-state structure of trans-N2CP exhibits pi-stacking column, while the Cu(III) complex shows 1-D rodlike hydrogen bonding chain comparable with the zigzag hydrogen-bonding chain of cis-derivatives.Entities:
Year: 2003 PMID： 14677928 DOI： 10.1021/ja038519t
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419