Literature DB >> 14671792

Recent developments in chiral anion mediated asymmetric chemistry.

Jérôme Lacour1, Virginie Hebbe-Viton.   

Abstract

Chemical reactions and processes often involve cationic prostereogenic or racemic reagents, intermediates or products. To afford instead non-racemic or enantiopure compounds, an asymmetric ion pairing of the cations with chiral anionic counterions can be considered. This review presents recent examples of the synthesis and use of chiral anions for stereoselective purposes.

Year:  2003        PMID: 14671792     DOI: 10.1039/b205251m

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN: 0306-0012            Impact factor:   54.564


  11 in total

1.  The progression of chiral anions from concepts to applications in asymmetric catalysis.

Authors:  Robert J Phipps; Gregory L Hamilton; F Dean Toste
Journal:  Nat Chem       Date:  2012-07-24       Impact factor: 24.427

2.  Asymmetric gold-catalyzed lactonizations in water at room temperature.

Authors:  Sachin Handa; Daniel J Lippincott; Donald H Aue; Bruce H Lipshutz
Journal:  Angew Chem Int Ed Engl       Date:  2014-08-14       Impact factor: 15.336

3.  A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.

Authors:  Nathan D Shapiro; F Dean Toste
Journal:  Synlett       Date:  2010-03-01       Impact factor: 2.454

4.  Tunable and Cooperative Catalysis for Enantioselective Pictet-Spengler Reaction with Varied Nitrogen-Containing Heterocyclic Carboxaldehydes.

Authors:  Yuk-Cheung Chan; Marcus H Sak; Scott A Frank; Scott J Miller
Journal:  Angew Chem Int Ed Engl       Date:  2021-10-07       Impact factor: 15.336

5.  Mechanism of amido-thiourea catalyzed enantioselective imine hydrocyanation: transition state stabilization via multiple non-covalent interactions.

Authors:  Stephan J Zuend; Eric N Jacobsen
Journal:  J Am Chem Soc       Date:  2009-10-28       Impact factor: 15.419

6.  Cu(I)-catalyzed diamination of conjugated olefins with tunable anionic counterions. A possible approach to asymmetric diamination.

Authors:  Baoguo Zhao; Haifeng Du; Yian Shi
Journal:  J Org Chem       Date:  2009-11-06       Impact factor: 4.354

7.  Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols through Intramolecular Hydroalkoxylation of Allenes.

Authors:  Weiwei Zi; F Dean Toste
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-30       Impact factor: 15.336

8.  Syntheses, Characterization, Resolution, and Biological Studies of Coordination Compounds of Aspartic Acid and Glycine.

Authors:  Temitayo Aiyelabola; Ezekiel Akinkunmi; Isaac Ojo; Efere Obuotor; Clement Adebajo; David Isabirye
Journal:  Bioinorg Chem Appl       Date:  2017-02-15       Impact factor: 7.778

9.  Enantiodivergent asymmetric catalysis with the tropos BIPHEP ligand and a proline derivative as chiral selector.

Authors:  P Oczipka; D Müller; W Leitner; G Franciò
Journal:  Chem Sci       Date:  2015-10-29       Impact factor: 9.825

10.  Enantiomerization of Axially Chiral Biphenyls: Polarizable MD Simulations in Water and Butylmethylether.

Authors:  Veronika Zeindlhofer; Phillip Hudson; Ádám Márk Pálvölgyi; Matthias Welsch; Mazin Almarashi; H Lee Woodcock; Bernard Brooks; Katharina Bica-Schröder; Christian Schröder
Journal:  Int J Mol Sci       Date:  2020-08-28       Impact factor: 5.923

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