| Literature DB >> 14664574 |
Shun-Ichi Murahashi1, Naruyoshi Komiya, Hiroyuki Terai, Takahiro Nakae.
Abstract
RuCl3-catalyzed oxidative cyanation of tertiary amines with sodium cyanide under molecular oxygen (1 atm) at 60 degrees C gives the corresponding alpha-aminonitriles, which are versatile synthetic intermediates of various compounds such as amino acids and unsymmetrical 1,2-diamines, in excellent yields. This reaction is clean and should be an environmentally benign and useful process.Entities:
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Year: 2003 PMID： 14664574 DOI： 10.1021/ja0390303
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419