Literature DB >> 14651100

Formation of nickel-thiolate aggregates via reaction with CH2Cl2.

Qiang Wang1, Andrew C Marr, Alexander J Blake, Claire Wilson, Martin Schröder.   

Abstract

Reaction of the mononuclear nickel-thiolate complex [Ni(L1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex [Ni5Cl2(L1)4(dppe)2], while [Ni(L1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L2)(dcpe)2] in which two L1 units are linked by a methylene group derived from CH2Cl2.

Entities:  

Year:  2003        PMID: 14651100     DOI: 10.1039/b309523a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Reversibility effects on the stereoselectivity of Pt(II)-mediated cascade poly-ene cyclizations.

Authors:  Jeremiah A Feducia; Michel R Gagné
Journal:  J Am Chem Soc       Date:  2007-12-21       Impact factor: 15.419

2.  Chemical issues addressing the construction of the distal Ni[cysteine-glycine-cysteine]2- site of acetyl CoA synthase: why not copper?

Authors:  Kayla N Green; Scott M Brothers; Boram Lee; Marcetta Y Darensbourg; David A Rockcliffe
Journal:  Inorg Chem       Date:  2009-04-06       Impact factor: 5.165

  2 in total

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