Literature DB >> 14649891

Stereospecificity in the silicon tethered alpha-(methyl)allylation of aldehydes.

Jeremy Robertson1, Michael J Hall, Stuart P Green.   

Abstract

Heating E- and Z-crotyl(diphenyl)silyloxy aldehydes, in the absence of an added catalyst, results in stereospecific intramolecular allyl transfer with moderate to high stereoselectivity.

Entities:  

Year:  2003        PMID： 14649891     DOI： 10.1039/b306920f

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  3 in total

1.  P-Tether-Mediated, Iterative SN2'-Cuprate Alkylation Strategy to Skipped Polyol Stereotetrads: Utility of an Oxidative "Function Switch" with Phosphite-Borane Tethers.

Authors:  Jana L Markley; Paul R Hanson
Journal:  Org Lett       Date:  2017-05-04       Impact factor: 6.005

2.  An Asymmetric Vinylogous Michael Cascade of Silyl Glyoximide, Vinyl Grignard, and Nitroalkenes via Long Range Stereoinduction.

Authors:  Gregory R Boyce; Jeffrey S Johnson
Journal:  J Org Chem       Date:  2016-02-02       Impact factor: 4.354

3.  Tether-directed synthesis of highly substituted oxasilacycles via an intramolecular allylation employing allylsilanes.

Authors:  Peter J Jervis; Liam R Cox
Journal:  Beilstein J Org Chem       Date:  2007-02-08       Impact factor: 2.883
  3 in total

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