Literature DB >> 14640623

Self-assembly of monodispersed, chiral nanoclusters of cysteine on the Au(110)-(1 x 2) surface.

Angelika Kühnle1, Trolle R Linderoth, Flemming Besenbacher.   

Abstract

The self-assembly of monodispersed supramolecular nanoclusters was observed by scanning tunneling microscopy (STM). The clusters form from the naturally occurring amino acid cysteine by vapor deposition onto the Au(110)-(1 x 2) surface under ultrahigh vacuum conditions. Enantiomerically pure l- and d-cysteine yields clusters with mirror-image STM signatures. Racemic ld-cysteine segregates into homochiral clusters, evidencing specific intermolecular interactions during the self-assembly process.

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Year:  2003        PMID: 14640623     DOI: 10.1021/ja0377403

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  2 in total

1.  Intermolecular interactions between gold clusters and selected amino acids cysteine and glycine: a DFT study.

Authors:  Hu-Jun Xie; Qun-Fang Lei; Wen-Jun Fang
Journal:  J Mol Model       Date:  2011-05-12       Impact factor: 1.810

2.  Surface-site reactivity in small-molecule adsorption: A theoretical study of thiol binding on multi-coordinated gold clusters.

Authors:  Elvis C M Ting; Tatiana Popa; Irina Paci
Journal:  Beilstein J Nanotechnol       Date:  2016-01-18       Impact factor: 3.649

  2 in total

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