| Literature DB >> 14640623 |
Angelika Kühnle1, Trolle R Linderoth, Flemming Besenbacher.
Abstract
The self-assembly of monodispersed supramolecular nanoclusters was observed by scanning tunneling microscopy (STM). The clusters form from the naturally occurring amino acid cysteine by vapor deposition onto the Au(110)-(1 x 2) surface under ultrahigh vacuum conditions. Enantiomerically pure l- and d-cysteine yields clusters with mirror-image STM signatures. Racemic ld-cysteine segregates into homochiral clusters, evidencing specific intermolecular interactions during the self-assembly process.Entities:
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Year: 2003 PMID: 14640623 DOI: 10.1021/ja0377403
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419