Literature DB >> 14640615

A triplet carbene surviving a week in solution at room temperature.

Eri Iwamoto1, Katsuyuki Hirai, Hideo Tomioka.   

Abstract

A stable triplet carbene, having a lifetime at 25 degrees C of 14.5 days in a dilute benzene solution, was realized by simply changing the substituent at the 10 position of the previously most persistent carbene, di[9-(10-phenyl)anthryl]carbene, from a phenyl to a 2,6-dimethyl-4-tert-butylphenyl group.

Entities:  

Year:  2003        PMID: 14640615     DOI: 10.1021/ja038423z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  2 in total

Review 1.  Porphyrinoids as a platform of stable radicals.

Authors:  Daiki Shimizu; Atsuhiro Osuka
Journal:  Chem Sci       Date:  2018-01-08       Impact factor: 9.825

2.  Highly brominated anthracenes as precursors for the convenient synthesis of 2,9,10-trisubstituted anthracene derivatives.

Authors:  Osman Cakmak; Leyla Aydogan; Kiymet Berkil; Ilhami Gulcin; Orhan Buyukgungor
Journal:  Beilstein J Org Chem       Date:  2008-12-10       Impact factor: 2.883

  2 in total

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