| Literature DB >> 14639650 |
Michael Prakesch1, Danielle Grée, René Grée, Jennifer Carter, Ilyas Washington, K N Houk.
Abstract
The cycloadditions of nitrile oxides with new and previously studied allylic fluorides were examined. The 1,3-dipolar cycloaddition reactions were also investigated theoretically with density functional theory (B3LYP) based transition-state modelling. The predictions provided reasonable agreement with experiment, indicating that both steric and electronic effects have important influences on the stereoselectivities of these reactions.Entities:
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Year: 2003 PMID： 14639650 DOI： 10.1002/chem.200304967
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236