Literature DB >> 14631049

High-performance solid Acid fuel cells through humidity stabilization.

Dane A Boysen1, Tetsuya Uda, Calum R I Chisholm, Sossina M Haile.   

Abstract

Although they hold the promise of clean energy, state-of-the-art fuel cells based on polymer electrolyte membrane fuel cells are inoperable above 100 degrees C, require cumbersome humidification systems, and suffer from fuel permeation. These difficulties all arise from the hydrated nature of the electrolyte. In contrast, "solid acids" exhibit anhydrous proton transport and high-temperature stability. We demonstrate continuous, stable power generation for both H2/O2 and direct methanol fuel cells operated at approximately 250 degrees C using a humidity-stabilized solid acid CsH2PO4 electrolyte.

Entities:  

Year:  2003        PMID: 14631049     DOI: 10.1126/science.1090920

Source DB:  PubMed          Journal:  Science        ISSN: 0036-8075            Impact factor:   47.728


  10 in total

1.  Mechanochemically synthesized CsH2PO4-H3PW12O40 composites as proton-conducting electrolytes for fuel cell systems in a dry atmosphere.

Authors:  Song-Yul Oh; Evan K Insani; Van H Nguyen; Go Kawamura; Hiroyuki Muto; Mototsugu Sakai; Atsunori Matsuda
Journal:  Sci Technol Adv Mater       Date:  2011-05-03       Impact factor: 8.090

2.  The mechanism of proton conduction in phosphoric acid.

Authors:  Linas Vilčiauskas; Mark E Tuckerman; Gabriel Bester; Stephen J Paddison; Klaus-Dieter Kreuer
Journal:  Nat Chem       Date:  2012-04-22       Impact factor: 24.427

3.  Characterization of the dynamics in the protonic conductor CsH₂PO₄ by ¹⁷O solid-state NMR spectroscopy and first-principles calculations: correlating phosphate and protonic motion.

Authors:  Gunwoo Kim; John M Griffin; Frédéric Blanc; Sossina M Haile; Clare P Grey
Journal:  J Am Chem Soc       Date:  2015-03-16       Impact factor: 15.419

4.  A composite membrane of caesium salt of heteropolyacids/quaternary Diazabicyclo-octane polysulfone with poly (tetrafluoroethylene) for intermediate temperature fuel cells.

Authors:  Chenxi Xu; Xu Wang; Xu Wu; Yuancheng Cao; Keith Scott
Journal:  Membranes (Basel)       Date:  2012-07-10

5.  Platinum-decorated carbon nanotubes for hydrogen oxidation and proton reduction in solid acid electrochemical cells.

Authors:  V Sara Thoi; Robert E Usiskin; Sossina M Haile
Journal:  Chem Sci       Date:  2014-12-22       Impact factor: 9.825

6.  Spontaneous formation of nanoparticles on electrospun nanofibres.

Authors:  Norbert Radacsi; Fernando Diaz Campos; Calum R I Chisholm; Konstantinos P Giapis
Journal:  Nat Commun       Date:  2018-11-09       Impact factor: 14.919

Review 7.  Properties and Applications of Metal Phosphates and Pyrophosphates as Proton Conductors.

Authors:  Rosario M P Colodrero; Pascual Olivera-Pastor; Aurelio Cabeza; Montse Bazaga-García
Journal:  Materials (Basel)       Date:  2022-02-09       Impact factor: 3.623

8.  Arrangement of water molecules and high proton conductivity of tunnel structure phosphates, KMg1-x H2x (PO3)3·yH2O.

Authors:  Yasuaki Matsuda; Kousei Funakoshi; Ryosuke Sebe; Genki Kobayashi; Masao Yonemura; Nobuyuki Imanishi; Daisuke Mori; Shinya Higashimoto
Journal:  RSC Adv       Date:  2020-02-24       Impact factor: 3.361

9.  Stability of Superprotonic CsH2PO4 Hermetically Sealed in Different Environments.

Authors:  Cristian E Botez; Israel Martinez; Alex D Price
Journal:  Materials (Basel)       Date:  2022-07-17       Impact factor: 3.748

10.  Enhanced MEA Performance for an Intermediate-Temperature Fuel Cell with a KH5(PO4)2-Doped Polybenzimidazole Membrane.

Authors:  Yifan Li; Jing Hu; Joan Papavasiliou; Zhiyong Fu; Li Chen; Haibin Li
Journal:  Membranes (Basel)       Date:  2022-07-23
  10 in total

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