Literature DB >> 14627426

Direct iodination of alkanes.

Raúl Montoro1, Thomas Wirth.   

Abstract

[reaction: see text] A cheap and efficient iodination of hydrocarbons can be achieved by generating tert-butyl hypoiodite from iodine and sodium tert-butoxide. The alkane is reactant and solvent, and this metal-free process provides a clean solution for their direct iodination.

Entities:  

Year:  2003        PMID： 14627426     DOI： 10.1021/ol0359012

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Synthesis of 2-oxindoles via 'transition-metal-free' intramolecular dehydrogenative coupling (IDC) of sp(2) C-H and sp(3) C-H bonds.

Authors:  Nivesh Kumar; Santanu Ghosh; Subhajit Bhunia; Alakesh Bisai
Journal:  Beilstein J Org Chem       Date:  2016-06-08       Impact factor: 2.883

2.  Selective transition-metal-free vicinal cis-dihydroxylation of saturated hydrocarbons.

Authors:  Luis Bering; Andrey P Antonchick
Journal:  Chem Sci       Date:  2016-08-22       Impact factor: 9.825

3.  Electrolytic copper as cheap and effective catalyst for one-pot triazole synthesis.

Authors:  Jacek Mularski; Barbara Czaplińska; Wioleta Cieślik; Jakub Bebłot; Piotr Bartczak; Rafał Sitko; Jarosław Polański; Robert Musiol
Journal:  Sci Rep       Date:  2018-03-14       Impact factor: 4.379

4.  β C-H di-halogenation via iterative hydrogen atom transfer.

Authors:  Ethan A Wappes; Avassaya Vanitcha; David A Nagib
Journal:  Chem Sci       Date:  2018-04-30       Impact factor: 9.825
  4 in total

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