Literature DB >> 14613147

On the mechanism of the laccase-mediator system in the oxidation of lignin.

Claudia Crestini1, Lubo Jurasek, Dimitris S Argyropoulos.   

Abstract

In an effort to elucidate the role of phenolic and non-phenolic lignin subunits in a laccase mediator (LM) system, vanillyl alcohol was oxidized with laccase in the presence and absence of the mediator 1-hydroxybenzotriazol (HBT). Furthermore, the role of phenolic, aliphatic hydroxyl, and carboxylic acid moieties in lignin degradation was elucidated by selectively blocking them. The modified samples were then subjected to laccase and laccase-HBT treatments. On the basis of this data it was possible to establish the role of this mediator. HBT mediates the oxidation of lignin by inducing side-chain oxidation and oxygen-addition products rather than oxidative coupling reactions.

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Year:  2003        PMID: 14613147     DOI: 10.1002/chem.200304818

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  7 in total

1.  A novel and efficient fungal delignification strategy based on versatile peroxidase for lignocellulose bioconversion.

Authors:  Wen Kong; Xiao Fu; Lei Wang; Ahmad Alhujaily; Jingli Zhang; Fuying Ma; Xiaoyu Zhang; Hongbo Yu
Journal:  Biotechnol Biofuels       Date:  2017-09-13       Impact factor: 6.040

2.  Use of laccase as a novel, versatile reporter system in filamentous fungi.

Authors:  Gerd J Mander; Huaming Wang; Elizabeth Bodie; Jens Wagner; Kay Vienken; Claudia Vinuesa; Caroline Foster; Abigail C Leeder; Gethin Allen; Valerie Hamill; Giselle G Janssen; Nigel Dunn-Coleman; Marvin Karos; Hans Georg Lemaire; Thomas Subkowski; Claus Bollschweiler; Geoffrey Turner; Bernhard Nüsslein; Reinhard Fischer
Journal:  Appl Environ Microbiol       Date:  2006-07       Impact factor: 4.792

3.  Potential of acetylacetone as a mediator for Trametes versicolor laccase in enzymatic transformation of organic pollutants.

Authors:  Hua Yang; Hongfei Sun; Shujuan Zhang; Bingdang Wu; Bingcai Pan
Journal:  Environ Sci Pollut Res Int       Date:  2015-03-14       Impact factor: 4.223

Review 4.  Stachybotrys chartarum-A Hidden Treasure: Secondary Metabolites, Bioactivities, and Biotechnological Relevance.

Authors:  Sabrin R M Ibrahim; Hani Choudhry; Amer H Asseri; Mahmoud A Elfaky; Shaimaa G A Mohamed; Gamal A Mohamed
Journal:  J Fungi (Basel)       Date:  2022-05-12

5.  Mechanistic insight in the selective delignification of wheat straw by three white-rot fungal species through quantitative 13C-IS py-GC-MS and whole cell wall HSQC NMR.

Authors:  Gijs van Erven; Nazri Nayan; Anton S M Sonnenberg; Wouter H Hendriks; John W Cone; Mirjam A Kabel
Journal:  Biotechnol Biofuels       Date:  2018-09-26       Impact factor: 6.040

Review 6.  Current Advances in Biodegradation of Polyolefins.

Authors:  Ni Zhang; Mingzhu Ding; Yingjin Yuan
Journal:  Microorganisms       Date:  2022-07-29

7.  Evidence for lignin oxidation by the giant panda fecal microbiome.

Authors:  Wei Fang; Zemin Fang; Peng Zhou; Fei Chang; Yuzhi Hong; Xuecheng Zhang; Hui Peng; Yazhong Xiao
Journal:  PLoS One       Date:  2012-11-28       Impact factor: 3.240

  7 in total

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