Literature DB >> 14602036

Catalytic, asymmetric synthesis of cyanohydrin ethyl carbonates.

Yuri N Belokon'1, A John Blacker, Lisa A Clutterbuck, Michael North.   

Abstract

[reaction: see text] The bimetallic titanium complex [(salen)TiO](2), where salen is the ligand derived from (R,R)-cyclohexanediamine and 3,5-di-tert-butyl-salicylaldehyde, has been shown to catalyze the asymmetric addition of ethyl cyanoformate to aldehydes leading to cyanohydrin carbonates with high enantiomeric excesses.

Entities:  

Year:  2003        PMID: 14602036     DOI: 10.1021/ol035828f

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Kinetics and mechanism of vanadium catalysed asymmetric cyanohydrin synthesis in propylene carbonate.

Authors:  Michael North; Marta Omedes-Pujol
Journal:  Beilstein J Org Chem       Date:  2010-11-03       Impact factor: 2.883

Review 2.  Chiral poly-rare earth metal complexes in asymmetric catalysis.

Authors:  Masakatsu Shibasaki
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2006-04       Impact factor: 3.493

3.  TBD- or PS-TBD-Catalyzed One-Pot Synthesis of Cyanohydrin Carbonates and Cyanohydrin Acetates from Carbonyl Compounds.

Authors:  Satoru Matsukawa; Junya Kimura; Miki Yoshioka
Journal:  Molecules       Date:  2016-08-10       Impact factor: 4.411

  3 in total

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