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Literature DB >> 14587708

Copper(II)-catalysed aerobic oxidation of primary alcohols to aldehydes.

Patrick Gamez¹, Isabel W C E Arends, Jan Reedijk, Roger A Sheldon.

Abstract

[CuBr2(2,2'-bipyridine)] catalyses the selective and very mild aerobic oxidation of primary alcohols to aldehydes in acetonitrile:water (2:1) in the presence of 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and a base as cocatalysts.

Entities: Chemical

Year: 2003 PMID： 14587708 DOI： 10.1039/b308668b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

19 in total

Review 1. Aerobic copper-catalyzed organic reactions.

Authors: Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal: Chem Rev Date: 2013-06-20 Impact factor: 60.622

2. Cu/Nitroxyl Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature.

Authors: Jinho Kim; Shannon S Stahl
Journal: ACS Catal Date: 2013-07-05 Impact factor: 13.084

3. Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols.

Authors: Jessica M Hoover; Shannon S Stahl
Journal: J Am Chem Soc Date: 2011-10-03 Impact factor: 15.419

4. Highly efficient Cu(I)-catalyzed oxidation of alcohols to ketones and aldehydes with diaziridinone.

Authors: Yingguang Zhu; Baoguo Zhao; Yian Shi
Journal: Org Lett Date: 2013-02-15 Impact factor: 6.005

Review 5. Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems.

Authors: Bradford L Ryland; Shannon S Stahl
Journal: Angew Chem Int Ed Engl Date: 2014-07-07 Impact factor: 15.336

10. Palladium supported on a novel ordered mesoporous polypyrrole/carbon nanocomposite as a powerful heterogeneous catalyst for the aerobic oxidation of alcohols to carboxylic acids and ketones on water.

Authors: Nasim Ganji; Babak Karimi; Sepideh Najafvand-Derikvandi; Hojatollah Vali
Journal: RSC Adv Date: 2020-04-03 Impact factor: 3.361

Copper(II)-catalysed aerobic oxidation of primary alcohols to aldehydes.

Review 1. Aerobic copper-catalyzed organic reactions.

2. Cu/Nitroxyl Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature.

3. Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols.

4. Highly efficient Cu(I)-catalyzed oxidation of alcohols to ketones and aldehydes with diaziridinone.

Review 5. Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems.

6. Development and comparison of the substrate scope of Pd-catalysts for the aerobic oxidation of alcohols.

7. Mechanism of alcohol oxidation mediated by copper(II) and nitroxyl radicals.

8. Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems.

9. Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation.

10. Palladium supported on a novel ordered mesoporous polypyrrole/carbon nanocomposite as a powerful heterogeneous catalyst for the aerobic oxidation of alcohols to carboxylic acids and ketones on water.