| Literature DB >> 14567708 |
Roald Hoffmann1, Sason Shaik, Philippe C Hiberty.
Abstract
Quantum mechanics has provided chemistry with two general theories, valence bond (VB) theory and molecular orbital (MO) theory. The two theories were developed at about the same time, but quickly diverged into rival schools that have competed, sometimes fervently, on charting the mental map and epistemology of chemistry. Three practitioners of MO and VB theory talk - fighting a little, trying to understand - of the past and present of these two approaches to describing bonding in molecules.Year: 2003 PMID: 14567708 DOI: 10.1021/ar030162a
Source DB: PubMed Journal: Acc Chem Res ISSN: 0001-4842 Impact factor: 22.384