Literature DB >> 14567708

A conversation on VB vs MO theory: a never-ending rivalry?

Roald Hoffmann1, Sason Shaik, Philippe C Hiberty.   

Abstract

Quantum mechanics has provided chemistry with two general theories, valence bond (VB) theory and molecular orbital (MO) theory. The two theories were developed at about the same time, but quickly diverged into rival schools that have competed, sometimes fervently, on charting the mental map and epistemology of chemistry. Three practitioners of MO and VB theory talk - fighting a little, trying to understand - of the past and present of these two approaches to describing bonding in molecules.

Year:  2003        PMID: 14567708     DOI: 10.1021/ar030162a

Source DB:  PubMed          Journal:  Acc Chem Res        ISSN: 0001-4842            Impact factor:   22.384


  4 in total

1.  Beyond the bond.

Authors:  Philip Ball
Journal:  Nature       Date:  2011-01-06       Impact factor: 49.962

Review 2.  Ultrashort metal-metal distances and extreme bond orders.

Authors:  Frank R Wagner; Awal Noor; Rhett Kempe
Journal:  Nat Chem       Date:  2009-09-23       Impact factor: 24.427

3.  Unified Model for Photophysical and Electro-Optical Properties of Green Fluorescent Proteins.

Authors:  Chi-Yun Lin; Matthew G Romei; Luke M Oltrogge; Irimpan I Mathews; Steven G Boxer
Journal:  J Am Chem Soc       Date:  2019-09-11       Impact factor: 15.419

4.  Models of necessity.

Authors:  Timothy Clark; Martin G Hicks
Journal:  Beilstein J Org Chem       Date:  2020-07-13       Impact factor: 2.883

  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.