Literature DB >> 14535821

Using cyanide to put noble gases inside C60.

R J Cross1, A Khong, M Saunders.   

Abstract

After fullerenes are heated in the presence of a noble gas or an unreactive molecule at 650 degrees C and 3000 atm pressure, a small fraction of the fullerene molecules contain the atom or molecule. The incorporation fraction is greatly enhanced by adding potassium cyanide to the reaction mixture. The details of the preparation are described here.

Entities:  

Year:  2003        PMID： 14535821     DOI： 10.1021/jo034851b

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Reversible Diels-Alder Addition to Fullerenes: A Study of Dimethylanthracene with H2@C60.

Authors:  Mahboob Subhani; Jinrong Zhou; Yuguang Sui; Huijing Zou; Michael Frunzi; James Cross; Martin Saunders; Cijun Shuai; Wenjie Liang; Hai Xu
Journal:  Nanomaterials (Basel)       Date:  2022-05-13       Impact factor: 5.719

2.  A Solid-State Intramolecular Wittig Reaction Enables Efficient Synthesis of Endofullerenes Including Ne@C60 , 3 He@C60 , and HD@C60.

Authors:  Gabriela Hoffman; Mark C Walkey; John Gräsvik; George R Bacanu; Shamim Alom; Sally Bloodworth; Mark E Light; Malcolm H Levitt; Richard J Whitby
Journal:  Angew Chem Int Ed Engl       Date:  2021-03-04       Impact factor: 15.336
  2 in total

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