Literature DB >> 14535811

Zn(II)-catalyzed thiolysis of oxiranes in water under neutral conditions.

Francesco Fringuelli1, Ferdinando Pizzo, Simone Tortoioli, Luigi Vaccaro.   

Abstract

Thiolysis of a variety of 1,2-epoxides in water at 30 degrees C and pH 7.0 is strongly accelerated by ZnCl(2) (10 mol %) except when amino- and carboxythiophenol are used. The aqueous medium and the catalyst were recovered and reused in various runs without affecting the efficiency of the process.

Entities:  

Year:  2003        PMID: 14535811     DOI: 10.1021/jo0348266

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  4 in total

Review 1.  Recent trends in ring opening of epoxides with sulfur nucleophiles.

Authors:  Sajjad Ahmad; Ameer Fawad Zahoor; Syed Ali Raza Naqvi; Muhammad Akash
Journal:  Mol Divers       Date:  2017-11-14       Impact factor: 2.943

Review 2.  Intermolecular difunctionalization of alkenes: synthesis of β-hydroxy sulfides.

Authors:  Bayan Azizi; Mohammad Reza Poor Heravi; Zinatossadat Hossaini; Abdolghaffar Ebadi; Esmail Vessally
Journal:  RSC Adv       Date:  2021-04-07       Impact factor: 3.361

3.  Synthesis of β-Hydroxysulfides from Thiophenols and Disulfides with tert-Butyl Hydroperoxide as the Oxidant and Reactant.

Authors:  Jian-Bo Feng; Xiao-Feng Wu
Journal:  ChemistryOpen       Date:  2016-05-17       Impact factor: 2.911

Review 4.  β-Hydroxy sulfides and their syntheses.

Authors:  Mokgethwa Bruce Marakalala; Edwin M Mmutlane; Henok H Kinfe
Journal:  Beilstein J Org Chem       Date:  2018-07-05       Impact factor: 2.883

  4 in total

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