Literature DB >> 14531653

Noncyclic [10-S-5] sulfuranide dioxide salts with three S-C bonds: a new class of stable hypervalent compounds.

Dmitri V Sevenard1, Alexander A Kolomeitsev, Berthold Hoge, Enno Lork, Gerd-Volker Röschenthaler.   

Abstract

Phenyl triflate reacts with CF3SiMe3/Q+F- (Q+ = [K(18-crown-6)]+, Me4N+) and (Me2N)3S+Me3SiF2- to afford the first noncyclic [10-S-5] sulfuranide dioxide salts, [(CF3)3SO2]-Q+, with three S-C bonds, whose molecular structure was determined by X-ray crystallography.

Entities:  

Year:  2003        PMID: 14531653     DOI: 10.1021/ja030155h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

1.  Olefination with Sulfonyl Halides and Esters: Synthesis of Unsaturated Sulfonyl Fluorides.

Authors:  Michał Tryniszewski; Dariusz Basiak; Michał Barbasiewicz
Journal:  Org Lett       Date:  2022-06-02       Impact factor: 6.072

  1 in total

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