Literature DB >> 14507213

Total synthesis of 10-norparvulenone and of O-methylasparvenone using a xanthate-mediated free radical addition-cyclization sequence.

Alejandro Cordero Vargas1, Béatrice Quiclet-Sire, Samir Z Zard.   

Abstract

[reaction: see text] A short synthesis of (+/-)-10-norparvulenone and (+/-)-O-methylasparvenone was developed starting from commercially available m-methoxyphenol, hinging on a xanthate-mediated addition-cyclization sequence for the construction of the alpha-tetralone subunit.

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Year:  2003        PMID: 14507213     DOI: 10.1021/ol035394o

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Some aspects of radical cascade and relay reactions.

Authors:  Béatrice Quiclet-Sire; Samir Z Zard
Journal:  Proc Math Phys Eng Sci       Date:  2017-04-05       Impact factor: 2.704

2.  Substituent effects on the rearrangements of cyclohexyl to cyclopentyl radicals involving avermectin-related radicals.

Authors:  Jennifer A R Luft; Tammo Winkler; Fiona M Kessabi; K N Houk
Journal:  J Org Chem       Date:  2008-10-09       Impact factor: 4.354

  2 in total

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