Literature DB >> 13678225

A rotaxane synthesis based on stilbene photoisomerization. A photoswitchable catch and release process.

Yuji Tokunaga1, Koichiro Akasaka, Kenji Hisada, Youji Shimomura, Suzuka Kakuchi.   

Abstract

A [2]rotaxane, having (Z)-alpha-methylstilbene as a stopper, is (1) synthesized in good yield by using a (E)- to (Z)-stilbene photoisomerization process, and (2) dissociated by reverse photoisomerization from (Z)- to (E)-stilbene.

Entities:  

Year:  2003        PMID: 13678225     DOI: 10.1039/b306349f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Threading-gated photochromism in [2]pseudorotaxanes.

Authors:  Giorgio Baggi; Lorenzo Casimiro; Massimo Baroncini; Serena Silvi; Alberto Credi; Stephen J Loeb
Journal:  Chem Sci       Date:  2019-04-23       Impact factor: 9.825

  1 in total

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