Literature DB >> 12971742

[Ge9=Ge9=Ge9=Ge9]8-: a linear tetramer of nine-atom germanium clusters, a nanorod.

Angel Ugrinov1, Slavi C Sevov.   

Abstract

A tetramer of nine-atom deltahedral germanium clusters and charge 8-, [Ge9=Ge9=Ge9=Ge9]8- , has been characterized as a (Rb-18C6)(+) salt (18C6 = 18-crown-6 polyether). The clusters are connected by pairs of parallel bonds, and the electrons are delocalized over the whole anion. The size of the tetramer is of nanorod dimensions, ca. 2 nm.

Entities:  

Year:  2003        PMID： 12971742     DOI： 10.1021/ic034677+

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  4 in total

1.  Photoelectron spectroscopic and computational studies of the Pt@Pb₁₀⁻¹ and Pt@Pb₁₂¹⁻/²⁻ anions.

Authors:  Andrej Grubisic; Haopeng Wang; Xiang Li; Yeon-Jae Ko; F Sanem Kocak; Mark R Pederson; Kit H Bowen; Bryan W Eichhorn
Journal:  Proc Natl Acad Sci U S A       Date:  2011-08-26       Impact factor: 11.205

2.  Synthesis of nine-atom deltahedral Zintl ions of germanium and their functionalization with organic groups.

Authors:  Miriam M Gillett-Kunnath; Slavi C Sevov
Journal:  J Vis Exp       Date:  2012-02-11       Impact factor: 1.355

3.  Chemi-Inspired Silicon Allotropes-Experimentally Accessible Si9 Cages as Proposed Building Block for 1D Polymers, 2D Sheets, Single-Walled Nanotubes, and Nanoparticles.

Authors:  Laura-Alice Jantke; Antti J Karttunen; Thomas F Fässler
Journal:  Molecules       Date:  2022-01-26       Impact factor: 4.411

4.  Symmetry collapse due to the presence of multiple local aromaticity in Ge244.

Authors:  Hong-Lei Xu; Nikolay V Tkachenko; Dariusz W Szczepanik; Ivan A Popov; Alvaro Muñoz-Castro; Alexander I Boldyrev; Zhong-Ming Sun
Journal:  Nat Commun       Date:  2022-04-20       Impact factor: 17.694
  4 in total

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