Literature DB >> 12968890

Concise synthesis, preparative resolution, absolute configuration determination, and applications of an atropisomeric biaryl catalyst for asymmetric acylation.

Alan C Spivey1, Fujiang Zhu, Mark B Mitchell, Stephen G Davey, Richard L Jarvest.   

Abstract

A new three-step synthesis and resolution of nucleophilic catalyst 1 suitable for large-scale preparation has been developed, and this catalyst has been shown to be effective for the kinetic resolution and asymmetric desymmetrization of a range of sec-alcohol substrates.

Entities:  

Year:  2003        PMID： 12968890     DOI： 10.1021/jo034603f

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  7 in total

1.  Kinetic resolution of secondary alcohols using amidine-based catalysts.

Authors:  Ximin Li; Hui Jiang; Eric W Uffman; Lei Guo; Yuhua Zhang; Xing Yang; Vladimir B Birman
Journal:  J Org Chem       Date:  2012-02-09       Impact factor: 4.354

2.  Enantioselective TADMAP-catalyzed carboxyl migration reactions for the synthesis of stereogenic quaternary carbon.

Authors:  Scott A Shaw; Pedro Aleman; Justin Christy; Jeff W Kampf; Porino Va; Edwin Vedejs
Journal:  J Am Chem Soc       Date:  2006-01-25       Impact factor: 15.419

Review 3.  Chirality in rotaxanes and catenanes.

Authors:  E M G Jamieson; F Modicom; S M Goldup
Journal:  Chem Soc Rev       Date:  2018-07-17       Impact factor: 54.564

4.  Site-selective catalysis of phenyl thionoformate transfer as a tool for regioselective deoxygenation of polyols.

Authors:  María Sanchez-Roselló; Angela L A Puchlopek; Adam J Morgan; Scott J Miller
Journal:  J Org Chem       Date:  2008-01-30       Impact factor: 4.354

5.  Asymmetric desymmetrization of meso-diols by C(2)-symmetric chiral 4-pyrrolidinopyridines.

Authors:  Hartmut Schedel; Keizo Kan; Yoshihiro Ueda; Kenji Mishiro; Keisuke Yoshida; Takumi Furuta; Takeo Kawabata
Journal:  Beilstein J Org Chem       Date:  2012-10-17       Impact factor: 2.883

6.  Enantioselective acyl transfer catalysis by a combination of common catalytic motifs and electrostatic interactions.

Authors:  Hiroki Mandai; Kazuki Fujii; Hiroshi Yasuhara; Kenko Abe; Koichi Mitsudo; Toshinobu Korenaga; Seiji Suga
Journal:  Nat Commun       Date:  2016-04-15       Impact factor: 14.919

7.  A convenient route to symmetrically and unsymmetrically substituted 3,5-diaryl-2,4,6-trimethylpyridines via Suzuki-Miyaura cross-coupling reaction.

Authors:  Dariusz Błachut; Joanna Szawkało; Zbigniew Czarnocki
Journal:  Beilstein J Org Chem       Date:  2016-04-28       Impact factor: 2.883
  7 in total

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