Literature DB >> 12967304

Titanocene-catalyzed regioselective syn-hydrosilation of alkynes.

Tamotsu Takahashi1, Fengyu Bao, Guohua Gao, Masamichi Ogasawara.   

Abstract

[reaction: see text] The titanium catalyst, which was generated in situ from titanocene dichloride and 2 equiv of butyllithium, was found to catalyze hydrosilation of a variety of alkynes with excellent regio- and syn-selectivity.

Entities:  

Year:  2003        PMID： 12967304     DOI： 10.1021/ol035277t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Cu(I)-catalyzed direct addition and asymmetric addition of terminal alkynes to imines.

Authors:  Chunmei Wei; Joel T Mague; Chao-Jun Li
Journal:  Proc Natl Acad Sci U S A       Date:  2004-04-05       Impact factor: 11.205

2.  Efficient and selective catalysis for hydrogenation and hydrosilation of alkenes and alkynes with PNP complexes of scandium and yttrium.

Authors:  Daniel S Levine; T Don Tilley; Richard A Andersen
Journal:  Chem Commun (Camb)       Date:  2017-10-31       Impact factor: 6.222

3.  Selective synthesis of E-vinylsilanes and E,E-divinylsilanes via platinum-catalyzed hydrosilylation of alkynes with secondary silanes.

Authors:  P Żak; M Bołt; C Pietraszuk
Journal:  RSC Adv       Date:  2018-11-30       Impact factor: 3.361

Review 4.  Enantioselective hydrogenations with chiral titanocenes.

Authors:  Oleksiy Vassylyev; Anthony Panarello; Johannes G Khinast
Journal:  Molecules       Date:  2005-07-14       Impact factor: 4.411
  4 in total

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