Literature DB >> 12967300

Cycloheptadiene ring synthesis by tandem intermolecular enyne metathesis.

Amol A Kulkarni1, Steven T Diver.   

Abstract

[reaction: see text] The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne.

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Year:  2003        PMID: 12967300     DOI: 10.1021/ol035246y

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Ruthenium Vinyl Carbene Intermediates in Enyne Metathesis.

Authors:  Steven T Diver
Journal:  Coord Chem Rev       Date:  2007-03-01       Impact factor: 22.315

2.  Ene-yne cross-metathesis with ruthenium carbene catalysts.

Authors:  Cédric Fischmeister; Christian Bruneau
Journal:  Beilstein J Org Chem       Date:  2011-02-04       Impact factor: 2.883

  2 in total

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