[The monomer electronic spectra and fluorescence spectra of some metal phthalocyanines].

The monomer electronic absorption spectra of the ZnPcS2P2 (disulfonated diphthalimidomethyl phthalocyanine zinc) in 11 kinds of solvents and 5 kinds of unsubstituted metal phthalocyanines in DMF were investigated. The monomer electronic absorption spectra of some substituted phthalocyanine zinc including ZnPcS4 (tetrasulfonated phthalocyanine zinc), ZnPcS4 (tetraphthalimidomethyl phthalocyanine zinc), ZnPc(NO2)4 (tetranitro phthalocyanine zinc) and ZnPcS2P2 in the same solvent were also studied. The result showed that (1) with the strengthening of coordination ability of the solvent, the maximum absorption wavelength of ZnPcS2P2 increased slightly. (2) with the increasing of electronegativity of central ion, the maximum absorption wavelength of MPcs had a little blue shift. (3) the electron-donating substituting group caused slightly blue shift. The monomer fluorescence spectra of ZnPcS4, ZnPcP4, and ZnPcS2P2 in different solvents were determined. The result showed that (1) the electron-withdrawing substituting group caused slightly red shift of the fluorescence spectra. (2) with the strenghtening of coordination ability of the solvent, the maximum emission wavelength increased slightly. (3) the fluorescence intensity of ZnPcS2P2 in the solution which contains Cremophor EL was remarkable stronger than that in other solvents. This is an important suggest to the development of photodynamic diagnose agent. The effect of solvents, central ions and substituents on spectra were partly explained by means of the quantrum chemistry.