Literature DB >> 12952447

The [2 + 4] Diels-Alder cycloadditon product of a probable dialuminene, Ar'AlAlAr' (Ar' = C(6)H(3)- 2,6-dipp(2); dipp = C(6)H(3)-2,6-Pr(i)(2)), with toluene.

Robert J Wright1, Andrew D Phillips, Philip P Power.   

Abstract

Reduction of Ar'AlI2 (Ar' = Ar'= C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) with KC8 in diethyl ether most probably affords the first "dialuminene", Ar'AlAlAr'; it was characterized by its reaction with toluene which yielded a [2 + 4] cycloaddition product incorporating the Ar'AlAlAr' unit.

Year:  2003        PMID： 12952447     DOI： 10.1021/ja034478p

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  A Diels-Alder super diene breaking benzene into C2H2 and C4H4 units.

Authors:  Yusuke Inagaki; Masaaki Nakamoto; Akira Sekiguchi
Journal:  Nat Commun       Date:  2014       Impact factor: 14.919

2.  Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules.

Authors:  Debabrata Dhara; Arumugam Jayaraman; Marcel Härterich; Rian D Dewhurst; Holger Braunschweig
Journal:  Chem Sci       Date:  2022-05-02       Impact factor: 9.969

3.  Carbon-chalcogen bond formation initiated by [Al(NONDipp)(E)]- anions containing Al-E{16} (E{16} = S, Se) multiple bonds.

Authors:  Matthew J Evans; Mathew D Anker; Claire L McMullin; Samuel E Neale; Nasir A Rajabi; Martyn P Coles
Journal:  Chem Sci       Date:  2022-03-31       Impact factor: 9.969

4.  Monomeric Cp3tAl(i): synthesis, reactivity, and the concept of valence isomerism.

Authors:  Alexander Hofmann; Tobias Tröster; Thomas Kupfer; Holger Braunschweig
Journal:  Chem Sci       Date:  2019-01-14       Impact factor: 9.825

5.  Ge=B π-Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes.

Authors:  Dominik Raiser; Christian P Sindlinger; Hartmut Schubert; Lars Wesemann
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-07       Impact factor: 15.336

Review 6.  Calcium-Catalyzed Arene C-H Bond Activation by Low-Valent AlI.

Authors:  Steffen Brand; Holger Elsen; Jens Langer; Samuel Grams; Sjoerd Harder
Journal:  Angew Chem Int Ed Engl       Date:  2019-09-13       Impact factor: 15.336

7.  Exploring Equilibria between Aluminium(I) and Aluminium(III): The Formation of Dihydroalanes, Masked Dialumenes and Aluminium(I) Species.

Authors:  Clare Bakewell; Katie Hobson; Claire J Carmalt
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-17       Impact factor: 16.823

8.  Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species.

Authors:  Debabrata Dhara; Felipe Fantuzzi; Marcel Härterich; Rian D Dewhurst; Ivo Krummenacher; Merle Arrowsmith; Conor Pranckevicius; Holger Braunschweig
Journal:  Chem Sci       Date:  2022-08-01       Impact factor: 9.969
  8 in total

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